Synthesis, formulation, and characterization of a bio-based paint derived from TOCN and polypyrrole

Malik, A., Barnabé, S. et Loranger, É. (2025). Synthesis, formulation, and characterization of a bio-based paint derived from TOCN and polypyrrole. Progress in Organic Coatings, 208 . Article 109511. ISSN 0300-9440 1873-331X DOI 10.1016/j.porgcoat.2025.109511

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Abstract

This study presents the development of a biobased paint by integrating TEMPO-oxidized cellulose nanofibers (TOCN) with polypyrrole (PPy) and incorporating polyvinyl alcohol (PVA) as a binder and glycerol as a plasticizer. The TOCN-PPy composite was synthesized via in-situ polymerization, followed by a washing process to ensure compositional purity. High-shear mixing and controlled thermal treatment produced homogeneous and stable formulations. Scanning Electron Microscopy (SEM) revealed a well-dispersed nanofiber network, with increased glycerol content contributing to smoother surface morphology. This may correlate with improved flexibility observed during handling. Raman analysis further confirmed the presence of polypyrrole and revealed spectral shifts associated with enhanced polymer dispersion and hydrogen bonding influenced by PVA and glycerol. Contact angle measurements showed that higher glycerol content increased wettability, reducing hydrophobicity and enhancing adaptability for coating applications. Thermogravimetric Analysis (TGA) revealed multi-stage degradation, with polypyrrole improving thermal stability. The enhanced flexibility observed in glycerol-containing samples is attributed to its plasticizing effect, as evidenced by morphological and handling observations. DSC was also employed for glass transition, melting and thermal decomposition behavior, and thermal stability trends. These findings emphasize the tunability of TOCN-PPy coatings, balancing structural integrity, thermal performance, and wettability for various industrial applications. The results also highlight the potential of TOCN-PPy composites as high-performance, eco-friendly coatings, supporting innovations in green chemistry and the circular bioeconomy.

Type de document:	Article
Mots-clés libres:	Biobased paint TEMPO-oxidized cellulose nanofibers (TOCN) Polypyrrole Polyvinyl alcohol Glycerol Circular bioeconomy
Date de dépôt:	29 mars 2026 14:50
Dernière modification:	29 mars 2026 14:50
Version du document déposé:	Version officielle de l'éditeur
URI:	https://depot-e.uqtr.ca/id/eprint/12765

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